Radium tracing of submarine groundwater discharge (SGD) and associated nutrient fluxes in a highly-permeable bed coastal zone, Korea   总被引：2，自引：0，他引：2  

Guebuem Kim  Jae-Woong Ryu  Dong-Woon Hwang 《Marine Chemistry》2008,109(3-4):307

In order to estimate submarine groundwater discharge (SGD) and SGD-driven nutrient fluxes, we measured the concentrations of nutrients, ²²⁴Ra, and ²²⁶Ra in seawater, river water, and coastal groundwater of Yeongil Bay (in the southeastern coast of Korea) in August 2004 and February 2005. The bottom sediments over the shallow areas of this bay are composed mainly of coarse sands. Large excess concentrations of ²²⁴Ra, ²²⁶Ra, and Si supplied from SGD were observed in August 2004, while these excess concentrations were not apparent in February 2005. Based on the mass balance for ²²⁴Ra, ²²⁶Ra, and Si, which showed conservative mixing behavior in seawater, SGD was estimated to be approximately 6 × 10⁶ m³ day^− 1 (seepage rate = 0.2 m day^− 1) in shallow areas (< 9 m water depth) in August 2004, which is much higher than the SGD level typically found in other coastal regions worldwide. During the summer period, SGD-driven nutrients in this bay contributed approximately 98%, 12%, and 76% of the total inputs for dissolved inorganic nitrogen (DIN), phosphorus (DIP), and silicate (DSi), respectively. Our study implies that the ecosystem in this highly permeable bed coastal zone is influenced strongly by SGD during summer, while such influences are negligible in winter.  相似文献   

Determining the O/O ratio of water using a water-CO₂ equilibration method: Application to glacial-interglacial changes in O-excess from the Dome Fuji ice core, Antarctica     

Ryu Uemura  Osamu Abe 《Geochimica et cosmochimica acta》2010,74(17):4919-7445

Recent studies show that oxygen three isotope measurement (¹⁶O, ¹⁷O, and ¹⁸O) of water provides additional information for investigating the hydrological cycle and paleoclimate. For determining the ¹⁸O/¹⁶O value of water, a conventional CO₂-water equilibration method involves measurement of the ratios of CO₂ isotopologues which were equilibrated with water. However, this long-established technique was not intended to measure the ¹⁷O/¹⁶O ratio, primarily because the historic ion correction scheme does not allow for possible deviations from a fixed (and mass-dependent) relationship between ¹⁷O/¹⁶O and ¹⁸O/¹⁶O isotope ratios. Here, we propose an improved method for obtaining the ¹⁷O/¹⁶O isotope ratio of fresh water by the equilibration method and measurement of the 45/44 CO₂ ion abundance ratio. Equations which we formulated for ¹⁷O/¹⁶O measurement have two features: first, instead of absolute isotope ratio (R), all equations are formulated in δ values, measured by isotope ratio mass spectrometry. Second, we include two “assigned” δ values of water standards in the equations, because the δ¹⁸O are commonly measured against two working standards to normalize the span of the δ scale. This approach clarifies that the contribution from ¹⁷O (¹²C¹⁶O¹⁷O⁺) to the molecular ion current at mass-to-charge ratio m/z 45 signal depends not on the absolute ¹³C/¹²C ratio, but on the relative δ¹³C differences between the working standards and the sample. The pH value of water affects δ¹⁷O estimation because δ¹³C of CO₂ was changed in the water-CO₂ system. We reevaluated this effect using a set of equations, which explicitly includes CO₂ partial pressure effect on pH value. Our new estimation of pH effect is significantly smaller than previously reported value, but it does not alter the main conclusions in the previous study. The method was verified by δ¹⁷O measurements of an international standard reference water (GISP) provided by the IAEA. We applied the method to investigate ¹⁷O-excess of the ice core drilled at the Dome Fuji station, Antarctica. A total of 1320 samples from a 130 m section around Marine Isotope Stage 9.3 (∼330,000 years before present) were measured. The error of a measurement for δ¹⁷O is 0.175‰ and that of ¹⁷O-excess is 184 per meg. Although these analytical uncertainties hampered accurate estimation of the changes in ¹⁷O-excess, the averaged data indicate that ¹⁷O-excess around MIS 9.3 was higher than during the subsequent glacial period. This approach can be applied only to fresh water samples, and additional improvements will be needed to measure samples which contains significant amount of carbonate minerals.  相似文献   

Speciation and behavior of arsenic in evaporation basins,California, USA     

Ji-Hun Ryu  Suduan Gao  Kenneth K. Tanji 《Environmental Earth Sciences》2010,61(8):1599-1612

Disposal of saline subsurface drainage waters from croplands into evaporation basins (or ponds) in the San Joaquin Valley of California causes excessive accumulation of salts and elevated concentrations of arsenic (As), a potentially high risk element with little information about its fate, in the agricultural evaporation ponds. We examined dissolved As concentration, speciation, and distribution in waters as well as As fractionation in sediments in the 10-cell South Evaporation Basin for better understanding of processes and conditions affecting As transformations and fate in a specific drainage disposal facility. The increase of total dissolved As concentrations were observed with higher Cl⁻ and electric conductivity along flow path indicating that evaporation was an important factor regulating total dissolved As concentration. The increases of reduced As species such as arsenite [As(III)] and organic As (monomethylarsonic acid and dimethylarsinic acid) were found towards the terminal flow pathway. However, arsenate [As(V)], the oxidized species remained greater than 67% of total dissolved As in all cell waters. Sequential extractions of sediments indicated that reducing conditions may influence As behavior in sediments to be more soluble and exchangeable. Arsenic association with oxides was appreciable only under oxidizing condition. Carbonate minerals played an important role in immobilizing As into the sediments under alkaline condition and a broad range of redox conditions. However, these sink mechanisms did not significantly reduce As concentrations in the cell waters. The reducing condition facilitated by high concentration of organic matter might be a major factor for the increase in As mobility.  相似文献   

Management and stability analysis of a seashore waste landfill site in Korea     

Yeon-Soo Jang  Jong-Sig Choi  Hye-Rim Ryu 《Environmental Earth Sciences》2010,61(1):87-92

Annual variation in the amount and composition of waste deposited in the Gimpo #2 landfill, the largest landfill around Seoul, Korea, is reviewed, and the stability of the same landfill is analyzed during waste disposal. For the stability analysis, three empirical stability prediction methods, i.e., linear stability, displacement velocity, and curve stability methods, are used to analyze field-measured settlement and horizontal displacement data. The analysis indicated that national waste management policy has greatly influenced the annual variation in the amount and composition of waste deposited in the landfill. Continuous measurement of geotechnical data and the use of stability analysis based on these data are necessary for landfills on seashore clay foundation. Stability of the landfill must be examined with various methods to ensure accurate determination of its stability.  相似文献   

Determination of perchlorate and iodide concentrations in edible seaweeds     

M. Yang  N. Her  J. Ryu  Y. Yoon 《International Journal of Environmental Science and Technology》2014,11(3):565-570

Perchlorate and iodide concentrations were determined in brown (Undaria pinnatifida and Laminaria japonica) and red (Porphyra sp.) edible seaweeds, which are commonly consumed by Korean people, with the use of ion chromatography, coupled with a tandem mass spectrometer. Seaweeds (i.e., good sources of iodine) are among the most important plant life in the ocean and commonly consumed as food and nutritional supplement in South Korea. All seaweed samples were purchased from different regions in South Korea. The detected concentrations of perchlorate were as follows: 19.7–620.7 μg kg^?1 dry weight (n = 11, mean concentration = 149.2 μg kg^?1 dry weight) for L. japonica and 7.3–21.7 μg kg^?1 dry weight (mean concentration = 10.6 μg kg^?1 dry weight) for U. pinnatifida. Of the 11 samples of Porphyra sp., only 1 sample showed 6.7 μg kg^?1 dry weight perchlorate. The concentrations of iodide in all seaweed samples varied from 0.44 to 6,800 mg kg^?1 dry weight. L. japonica samples (n = 11) had significantly higher iodide concentrations, with a mean of 5,261 mg kg^?1 dry weight. The bioconcentration factor values for perchlorate and iodide in the three different seaweeds varied widely and showed similar variation trends. The trend for perchlorate and iodide was Porphyra sp. < U. pinnatifida < L. japonica. The results have provided growing evidence that perchlorate frequently occurs in food products.  相似文献   

Estimation of net accumulation rate at a Patagonian glacier by ice core analyses using snow algae     

Shiro Kohshima  Nozomu Takeuchi  Jun Uetake  Takayuki Shiraiwa  Ryu Uemura  Naohiro Yoshida  Sumito Matoba  Maria Angelica Godoi 《Global and Planetary Change》2007,59(1-4):236

Snow algae in a 45.97-m-long ice core from the Tyndall Glacier (50°59′05″S, 73°31′12″W, 1756 m a.s.l.) in the Southern Patagonian Icefield were examined for potential use in ice core dating and estimation of the net accumulation rate. The core was subjected to visual stratigraphic observation and bulk density measurements in the field, and later to analyses of snow algal biomass, water isotopes (¹⁸O, D), and major dissolved ions. The ice core contained many algal cells that belonged to two species of snow algae growing in the snow near the surface: Chloromonas sp. and an unknown green algal species. Algal biomass and major dissolved ions (Na⁺, K⁺, Mg²⁺, Ca²⁺, Cl⁻, SO₄²⁻) exhibited rapid decreases in the upper 3 m, probably owing to melt water elution and/or decomposition of algal cells. However, seasonal cycles were still found for the snow algal biomass, ¹⁸O, D-excess, and major ions, although the amplitudes of the cycles decreased with depth. Supposing that the layers with almost no snow algae were the winter layers without the melt water essential to algal growth, we estimated that the net accumulation rate at this location was 12.9 m a^− 1 from winter 1998 to winter 1999, and 5.1 m from the beginning of winter to December 1999. These estimates are similar to the values estimated from the peaks of ¹⁸O (17.8 m a^− 1 from summer 1998 to summer 1999 and 11.0 m from summer to December 1999) and those of D-excess (14.7 m a^− 1 from fall 1998 to fall 1999 and 8.6 m a^− 1 from fall to December 1999). These values are much higher than those obtained by past ice core studies in Patagonia, but are of the same order of magnitude as those predicted from various observations at ablation areas of Patagonian glaciers.  相似文献   

Shock waves in the large-scale structure of the Universe     

Dongsu Ryu  Hyesung Kang 《Astrophysics and Space Science》2009,322(1-4):65-70

Cosmological shock waves are induced during hierarchical formation of large-scale structure in the universe. Like most astrophysical shocks, they are collisionless, since they form in the tenuous intergalactic medium through electromagnetic viscosities. The gravitational energy released during structure formation is transferred by these shocks to the intergalactic gas as heat, cosmic-rays, turbulence, and magnetic fields. Here we briefly described the properties and consequences of the shock waves in the context of the large-scale structure of the universe.  相似文献   

Impact of flooded rice paddy on remotely sensed evapotranspiration in the Krishna River basin,India     

Pardhasaradhi Teluguntla  Dongryeol Ryu  Biju George  Jeffrey P. Walker 《水文研究》2020,34(10):2190-2199

Evapotranspiration (ET) is one of the major water exchange processes between the earth's surface and the atmosphere. ET is a combined process of evaporation from open water bodies, bare soil and plant surfaces, and transpiration from vegetation. Remote sensing-based ET models have been developed to estimate spatially distributed ET over large regions, however, many of them reportedly underestimate ET over semi-arid regions (Jamshidi et al., Journal of Hydrometeorology, 2019, 20, 947–964). In this work, we show that underestimation of ET can occur due to the open water evaporation from flooded rice paddies ignored in the existing ET models. To address the gap in ET estimation, we have developed a novel approach that accounts for the missing ET component over flooded rice paddies. Our method improved ET estimates by a modified Penman-Monteith algorithm that considered the fraction of open water evaporation from flooded rice paddies. Daily ET was calculated using ground based meteorological data and the MODIS satellite data over the Krishna River Basin. Seasonal and annual ET values over the Krishna Basin were compared with two different ET algorithms. ET estimates from these two models were also compared for different crop combinations. Results were validated with flux tower-based measurements from other studies. We have identified a 17 mm/year difference in average annual ET over the Krishna River Basin with this new ET algorithm. This is very critical in basin scale water balance analysis and water productivity studies.  相似文献   

Statistical prediction of heavy rain in South Korea     

Keon Tae SOHN  Jeong Hyeong LEE  Soon Hwan LEE  Chan Su RYU 《大气科学进展》2005,22(5):703-710

1. Introduction In recent decades, extreme weather events seem to be growing in frequency and risk due to water-related disasters. According to the World Meteorological Or- ganization report (ISDR and WMO, 2004) on World Water Day, 22 March 2004, the economic losses caused by water-related disasters, including floods, droughts and tropical cyclones, are on an increasing trend as follows: the yearly mean in the 1970s was about 131 billion US dollars, 204 billion dollars in the 1980s, and …  相似文献   

Cosmic ray spectrum from diffusive shock acceleration     

Hyesung Kang  Dongsu Ryu 《Astrophysics and Space Science》2011,333(1):263-268

Nonlinear propagation of cylindrical and spherical dust-acoustic solitons in an unmagnetized dusty plasma consisting of cold dust grains, superthermal ions and electrons are investigated. For this purpose, the standard reductive perturbation method is employed to derive the cylindrical/spherical Korteweg-de-Vries equation which governs the dynamics of dust-acoustic solitons. The effects of nonplanar geometry and superthermal distributions on the cylindrical and spherical dust acoustic solitons structures are also studied by numerical calculation of the cylindrical/spherical Korteweg-de-Vries equation.  相似文献